13-R/S-tert-Butyldimethylsilyloxy-14,15-dinor-labd-8-ene-6α,7α-diol

13-R/S-tert-Butyldimethylsilyloxy-14,15-dinor-labd-8-ene-6α,7α-diol

Common Name: 13-R/S-tert-Butyldimethylsilyloxy-14,15-dinor-labd-8-ene-6α,7α-diol

Synonyms:

CAS Registry Number:

InChI: InChI=1S/C24H46O3Si/c1-16(27-28(9,10)22(3,4)5)12-13-18-17(2)19(25)20(26)21-23(6,7)14-11-15-24(18,21)8/h16,19-21,25-26H,11-15H2,1-10H3/t16?,19-,20-,21-,24+/m0/s1

InChIKey: InChIKey=FDKJHWHSJRBCBM-NAMRPVIISA-N

Formula: C24H46O3S1

Molecular Weight: 414.687236

Exact Mass: 414.316766

NMR Solvent: CDCl3

MHz:

Calibration:

NMR references: 13C - Marcos, I.S., Castaneda, L., Basabe, P., Diez, D., Urones, J.G. Tetrahedron (2008) 64, 8815-29

Species:

Notes: Family : Terpenoids, Type : Diterpenoids, Group : Labdanes; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)

Carbon NMR Peaks

Position PPM
1 (CH2) 39.4
2 (CH2) 18.9
3 (CH2) 43.9
4 (C) 33.6
5 (CH) 54
6 (CH) 74.9
7 (CH) 80.4
8 (C) 126.2
9 (C) 144.4
10 (C) 42.4
11 (CH2) 24.5
12 (CH2) 39.7
13 (CH) 69.2
16 (CH3) 23.8
17 (CH3) 14.8
18 (CH3) 33.6
19 (CH3) 22.4
20 (CH3) 21.6
13a (C) 26.1
13b (CH3) 18.3
13c (CH3) 18.3
13d (CH3) 4.2
13e (CH3) 4.5
13f (CH3) 4.5