15-tert-Butyldimethylsilyloxy-labda-8,13E-dien-6β,7β-diol

15-tert-Butyldimethylsilyloxy-labda-8,13E-dien-6β,7β-diol

Common Name: 15-tert-Butyldimethylsilyloxy-labda-8,13E-dien-6β,7β-diol

Synonyms:

CAS Registry Number:

InChI: InChI=1S/C26H48O3Si/c1-18(14-17-29-30(9,10)24(3,4)5)12-13-20-19(2)21(27)22(28)23-25(6,7)15-11-16-26(20,23)8/h14,21-23,27-28H,11-13,15-17H2,1-10H3/b18-14+/t21-,22-,23+,26-/m1/s1

InChIKey: InChIKey=DQNTXGLMFJDTHW-WDJIMQAPSA-N

Formula: C26H48O3S1

Molecular Weight: 440.724589

Exact Mass: 440.332416

NMR Solvent: CDCl3

MHz:

Calibration:

NMR references: 13C - Marcos, I.S., Castaneda, L., Basabe, P., Diez, D., Urones, J.G. Tetrahedron (2008) 64, 8815-29

Species:

Notes: Family : Terpenoids, Type : Diterpenoids, Group : Labdanes; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)

Carbon NMR Peaks

Position PPM
1 (CH2) 39.6
2 (CH2) 19.2
3 (CH2) 43
4 (C) 33.9
5 (CH) 53.1
6 (CH) 67.9
7 (CH) 73.4
8 (C) 125.4
9 (C) 144
10 (C) 40.1
11 (CH2) 26.9
12 (CH2) 39.9
13 (C) 137.7
14 (CH) 124.2
15 (CH2) 60.6
16 (CH3) 16.6
17 (CH3) 15.1
18 (CH3) 33.8
19 (CH3) 24.1
20 (CH3) 22
15a (C) 26.3
15b (CH3) 18.7
15c (CH3) 18.7
15d (CH3) 4.8
15e (CH3) 4.8
15f (CH3) 4.8