15-tert-Butyldimethylsilyloxy-labda-8,13Z-diene-6β,7β-diol

15-tert-Butyldimethylsilyloxy-labda-8,13Z-diene-6β,7β-diol

Common Name: 15-tert-Butyldimethylsilyloxy-labda-8,13Z-diene-6β,7β-diol

Synonyms:

CAS Registry Number:

InChI: InChI=1S/C26H48O3Si/c1-18(14-17-29-30(9,10)24(3,4)5)12-13-20-19(2)21(27)22(28)23-25(6,7)15-11-16-26(20,23)8/h14,21-23,27-28H,11-13,15-17H2,1-10H3/b18-14-/t21-,22-,23+,26-/m1/s1

InChIKey: InChIKey=DQNTXGLMFJDTHW-SBANUHDHSA-N

Formula: C26H48O3S1

Molecular Weight: 440.724589

Exact Mass: 440.332416

NMR Solvent: C+C

MHz:

Calibration:

NMR references: 13C - Marcos, I.S., Castaneda, L., Basabe, P., Diez, D., Urones, J.G. Tetrahedron (2008) 64, 8815-29

Species:

Notes: Family : Terpenoids, Type : Diterpenoids, Group : Labdanes; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)

Carbon NMR Peaks

Position PPM
1 (CH2) 40.1
2 (CH2) 19.2
3 (CH2) 43
4 (C) 33.9
5 (CH) 53.1
6 (CH) 67.9
7 (CH) 73.4
8 (C) 125.6
9 (C) 143.9
10 (C) 40.1
11 (CH2) 27
12 (CH2) 32.2
13 (C) 138.2
14 (CH) 125.1
15 (CH2) 60.3
16 (CH3) 23.6
17 (CH3) 15.1
18 (CH3) 33.8
19 (CH3) 24.2
20 (CH3) 22.1
15a (C) 26.3
15b (CH3) 18.7
15c (CH3) 18.7
15d (CH3) 1.3
15e (CH3) 4.8
15f (CH3) 4.8