(3S)-3alpha-Hydroxy-5alpha-acetoxy-6,6,9abeta-trimethyl-9beta-(4-methoxy-trans-cinnamoyloxy)-1,3,5,5aalpha,6,7,8,9,9a,9balpha-decahydronaphtho[1,2-c]furan-1-one

(3S)-3alpha-Hydroxy-5alpha-acetoxy-6,6,9abeta-trimethyl-9beta-(4-methoxy-trans-cinnamoyloxy)-1,3,5,5aalpha,6,7,8,9,9a,9balpha-decahydronaphtho[1,2-c]furan-1-one

Common Name: (3S)-3alpha-Hydroxy-5alpha-acetoxy-6,6,9abeta-trimethyl-9beta-(4-methoxy-trans-cinnamoyloxy)-1,3,5,5aalpha,6,7,8,9,9a,9balpha-decahydronaphtho[1,2-c]furan-1-one

Synonyms: (3S)-3alpha-Hydroxy-5alpha-acetoxy-6,6,9abeta-trimethyl-9beta-(4-methoxy-trans-cinnamoyloxy)-1,3,5,5aalpha,6,7,8,9,9a,9balpha-decahydronaphtho[1,2-c]furan-1-one

CAS Registry Number:

InChI: InChI=1S/C27H32O8/c1-15(28)33-19-14-18-22(25(31)35-24(18)30)27(4)20(12-13-26(2,3)23(19)27)34-21(29)11-8-16-6-9-17(32-5)10-7-16/h6-11,14,19-20,22-24,30H,12-13H2,1-5H3/b11-8+/t19-,20+,22+,23-,24-,27+/m0/s1

InChIKey: InChIKey=SUCIPERVLBGTBD-IGMKLNLTSA-N

Formula: C27H32O8

Molecular Weight: 484.539213

Exact Mass: 484.209718

NMR Solvent: CDCl3

MHz:

Calibration:

NMR references: 13C - Fomekong-Fotsop, D., Roussi, F., Callonec, C.L., Bousserouel, H., Litaudon, M., Guéritte, F. Tetrahedron (2008) 64, 2192-7

Species:

Notes: Family : Terpenoids, Type : Sesquiterpenoids, Group : Drimanes; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)

Carbon NMR Peaks

Position PPM
1 (CH) 79.3
2 (CH2) 24.3
3 (CH2) 39.9
4 (C) 33.9
5 (CH) 53
6 (CH) 69.8
7 (CH) 131.6
8 (C) 144.5
9 (CH) 57.2
10 (C) 43.7
11 (C) 166.4
12 (CH) 99.7
13 (CH3) 33.1
14 (CH3) 22.3
15 (CH3) 11.5
1' (C) 166.7
2' (CH) 115.4
3' (CH) 144.6
4' (C) 128.6
5' (CH) 129.9
6' (CH) 114.4
7' (C) 161.6
8' (CH) 114.4
9' (CH) 129.9
6a (C) 170.4
6b (CH3) 21.4
7'a (CH3) 55.4