Common Name: (4aR)-3-(1-Hydroxy-1-methylethyl)-5alpha-(formyloxy)-5,8abeta-dimethyl-6alpha-[[(2S,3S)-2,3-dimethyloxirane-2-yl]carbonyloxy]-1,2,4aalpha,5,6,7,8,8a-octahydronaphthalene-2-one
Synonyms: (4aR)-3-(1-Hydroxy-1-methylethyl)-5alpha-(formyloxy)-5,8abeta-dimethyl-6alpha-[[(2S,3S)-2,3-dimethyloxirane-2-yl]carbonyloxy]-1,2,4aalpha,5,6,7,8,8a-octahydronaphthalene-2-one
CAS Registry Number:
InChI: InChI=1S/C21H30O7/c1-12-20(5,28-12)17(24)27-16-7-8-19(4)10-14(23)13(18(2,3)25)9-15(19)21(16,6)26-11-22/h9,11-12,15-16,25H,7-8,10H2,1-6H3/t12-,15+,16+,19+,20-,21-/m0/s1
InChIKey: InChIKey=VPJNAZAFPFWEKA-FJBYUCRNSA-N
Formula: C21H30O7
Molecular Weight: 394.459511
Exact Mass: 394.199153
NMR Solvent: CDCl3
MHz:
Calibration:
NMR references: 13C - Vera, N., Misico, R., Sierra, M.G., Asakawa, Y., Bardon, A. Phytochemistry (2008) 69, 1689-94
Species:
Notes: Family : Terpenoids, Type : Sesquiterpenoids, Group : Eudesmanes; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)
Position | PPM |
---|---|
1 (CH2) | 31.9 |
2 (CH2) | 23.1 |
3 (CH) | 72.9 |
4 (C) | 82.6 |
5 (CH) | 59.6 |
6 (CH) | 140.6 |
7 (C) | 145.5 |
8 (C) | 199.8 |
9 (CH2) | 48.4 |
10 (C) | 39.1 |
11 (C) | 71.7 |
12 (CH3) | 29.1 |
13 (CH3) | 28.7 |
14 (CH3) | 18.1 |
15 (CH3) | 19.1 |
3a (C) | 168.2 |
3b (C) | 59.8 |
3c (CH) | 59.7 |
3d (CH3) | 13.8 |
3ba (CH3) | 19.1 |
4a (CH) | 159 |