Common Name: (alphaR,3S,9abeta)-alpha-Methyl-3beta-[(2R)-4beta-methyl-5-oxotetrahydrofuran-2beta-yl]-5-oxo-8beta-methoxy-9-hydroxyoctahydro-1H-pyrrolo[1,2-a]azepine-9beta-propanoic acid lactone
Synonyms: (alphaR,3S,9abeta)-alpha-Methyl-3beta-[(2R)-4beta-methyl-5-oxotetrahydrofuran-2beta-yl]-5-oxo-8beta-methoxy-9-hydroxyoctahydro-1H-pyrrolo[1,2-a]azepine-9beta-propanoic acid lactone
CAS Registry Number:
InChI: InChI=1S/C19H27NO6/c1-10-8-13(25-17(10)22)12-4-5-14-19(9-11(2)18(23)26-19)15(24-3)6-7-16(21)20(12)14/h10-15H,4-9H2,1-3H3/t10-,11-,12+,13-,14+,15-,19-/m1/s1
InChIKey: InChIKey=SVAFDCPXRYDWHM-SNEAAGIJSA-N
Formula: C19H27N1O6
Molecular Weight: 365.421555
Exact Mass: 365.183838
NMR Solvent:
MHz:
Calibration:
NMR references: 13C - Sanchez-Izquierdo, F., Blanco, P., Busque, F., Alibes, R., March, P.D., Figueredo, M., Font, J., Parella, T. Org Lett (2007) 9, 1769-72
Species:
Notes: Family : Alkaloids, Type : Stemona, Group : Croomines; 13 C Spectrum from Naproc 13: José Luis López-Pérez, Roberto Therón, Esther del Olmo, David Díaz: NAPROC-13: a database for the dereplication of natural product mixtures in bioassay-guided protocols. Bioinformatics 23(23):3256-3257 (2007)
Position | PPM |
---|---|
1 (CH2) | 25.3 |
2 (CH2) | 25.6 |
3 (CH) | 66.5 |
5 (C) | 51.1 |
6 (CH2) | 28.7 |
7 (CH2) | 26.8 |
8 (CH) | 87.6 |
9 (C) | 91 |
9a (CH) | 70 |
10 (CH2) | 35.3 |
11 (CH) | 35.8 |
12 (C) | 181 |
13 (CH3) | 16.8 |
14 (CH) | 76.9 |
15 (CH2) | 34.2 |
16 (CH) | 35.5 |
17 (C) | 179.2 |
18 (CH3) | 15.2 |
8a (CH3) | 57.5 |