psilotin

psilotin

Common Name: psilotin

Synonyms:

CAS Registry Number: 4624-53-7

InChI:

InChIKey:

Formula: C17H20O8

Molecular Weight: 352.3359

Exact Mass: 352.115818

NMR Solvent: CD3OD

MHz: 250.0

Calibration:

NMR references: Achenbach H., Witzke J. (1981) Synthese von Psilotin und 6-Epipsilotin. Liebigs Ann. Chem, 2384-2391.

Species:

Notes: McInnes A.G., Yoshida S., and Towers G.H.N. (1965) A phenolic glycoside from Psilotum nudun (L) Griseb reported first isolation from P. nudum

Proton NMR Peaks

Position PPM Peak Type J (Hz)
(1H) 7.4 d 9
7.13 d 9
4 (3H) 7.11 m
3 6.09 ddd 10, 2.5, 1
6 (1H) 5.48 dd 10.5, 5.5
OH, 1` 4.9
6`A(1H) 3.9 dd 11.5, 1.5
6`B(1H) 3.69 dd 11.5, 4.5
(4H) 3.4 m
(2H) 2.65 m

Carbon NMR Peaks

Position PPM
2 167.02
10 159.39
4 148.23
7 134.12
8 128.8
12 128.8
3 121.63
9 118
11 118
1` 102.39
6 80.88
3` 78.29
5` 78.13
2` 75.02
4` 71.52
6` 62.68
5 32.42